阿司匹林的合成条件研究

以水杨酸和醋酐为原料经O-酰化反应合成阿司匹林，比较了三氯化铝、三氯化铋和无水碳酸钠三种不同催化剂以及反应条件对合成的影响，找到了最佳催化剂和最佳反应务件，即以三氯化铝为催化剂，其用量为水杨酸的2％，水杨酸与醋酐的摩尔比为1：2，反应时间为30min，回流温度为85℃左右，阿司匹林产率可迭72．6％。实验表明该催化剂催化效果好．不污染环境，是一种环境友好的催化剂。同时，本法简单、快速、经济、无污染，产品质量好，适于工业化生产。     

基于Landsat TM数据的北京城市热岛研究

利用Landsat TM热红外波段数据，根据辐射传输方程反演得到北京地区地表温度，讨论了北京城市热岛现象及其与土地覆盖类型和植被指数的关系。结果显示，北京城区地表温度明显比郊区地表温度高。通过地表温度对比分析发现，城区平均地表温度比近郊区和远郊区地表温度分别高出4．5℃和9℃，城市热岛效应明显。城区不同地表覆盖类型的地表温度也有显著差异，城市地表温度与NDVI具有明显的负相关关系，城市地表植被覆盖度低是城市热岛出现的主要原因。     

A High-K, Mantle Derived Plutonic Suite from 'Linga', near Arequipa (Peru)

The Linga Group consists of a suite of Cretaceous high-K calc-alkalinerocks intruded into 2?0 Ga old basement in S.E. Peru. The rocksrange in composition from gabbros, through diorites and grandioritesto granites. Microprobe, major and trace element and isotopedata suggest the suite evolved by fractional crystallization,with plagioclase as the dominant phase and with surprisinglylittle interaction with the pre-existing crust. The rocks yieldan Rb/Sr whole rock isochron of 68 ? 3 Ma with an initial Sr-isotoperatio 0.70516 ? 8, and from three Nd-isotope analyses initialNd = – 1?4 to – 2?0. ¹⁸ O increases from 5?0 permil in a gabbro to 7?0 per mil in a granite, and models arepresented which suggest that the suite evolved from parentalmagmas which had ¹⁸O = 5?8 to 6?0 per mil, 1.5 per cent K₂O,63 p.p.m. Rb, 582 p.p.m. Sr, 35 p.p.m. Ce, 0.38 p.p.m. Ta, ⁸⁷Sr/⁸⁶Sr= 0.7052, and ¹⁴³Nd/¹⁴⁴Nd = 0.51247. Trace element considerationsimply that these magmas contain contributions from incompatibleelement enriched upper mantle material and from a componentassociated with subduction. The latter is thought to reflectthe preferential mobilization of alkali and alkaline earth elementsby H₂O-rich fluids from the subducted slab, and preliminarycalculations indicate that it was responsible for {small tilde}45 per cent of the Sr and {small tilde} 80 per cent of the Kin the more primitive Linga rocks. However, the isotope datasuggest that while the fluids may be from the subducted slab,the elements in this component may also have been mobilizedfrom the overlying mantle wedge.     

A Chemical and Multi-Isotope Study of the Western Cape Olivine Melilitite Province, South Africa: Implications for the Sources of Kimberlites and the Origin of the HIMU Signature in Africa

We present major and trace element and Sr–Nd–Pb–Hf–Osisotopic data for the 76–58 Ma Western Cape melilititeprovince, an age-progressive magmatic lineation in which primitiveolivine melilitite intrusives and alkali basalt lavas have beenemplaced on the southwestern margin of South Africa. The magmasrange from alkali basalts with strong HIMU isotopic and traceelement affinities on the continental shelf to melilitites withkimberlite-like incompatible element compositions and EM 1 isotopicaffinities on thick Proterozoic lithosphere (i.e. ⁸⁷Sr/⁸⁶Sr_i= 0·7029–0·7043,     

中国春季土壤湿度与东亚夏季风的关系

利用1981～2002年全国土壤湿度资料,利用相关分析发现东亚夏季风和河套地区及西南地区春季土壤湿度之间存在较大的正相关,利用这两个区域的春季土壤湿度定义了一个标准化春季土壤湿度指数（SMI）,结果发现：（1）SMI和东亚夏季风的强弱相关较好。高指数年东亚季风区低空西南夏季风气流和高层东风气流明显偏强,表明这一年夏季风偏强,低指数年则相反;（2）强SMI年,西太平洋副热带高压位置偏北,强度偏弱,西风扰动带偏北,有利于夏季风北推,不利于北方冷空气南下与之交汇,使得锋区偏北,位于华北、东北地区。弱SMI年则反之;（3）SMI能够较好地反映东部地区夏季降水,在强SMI年,长江流域降水明显偏少,而华北和河套地区的降水明显增多,而弱SMI年正好相反,这与东亚夏季风降水的环流形势也较为吻合（;4）SMI指数存在明显的4～6年和准2年的周期振荡,但其振幅和周期又有明显的周期变化。在对东亚夏季风强度的预报能力上,负的SMI对弱东亚夏季风的预报能力要强于正SMI对强东亚夏季风的预报能力。     

Hafnium Isotope and Trace Element Constraints on the Nature of Mantle Heterogeneity beneath the Central Southwest Indian Ridge (13{degrees}E to 47{degrees}E)

Hafnium isotope and incompatible trace element data are presentedfor a suite of mid-ocean ridge basalts (MORB) from 13 to 47°Eon the Southwest Indian Ridge (SWIR), one of the slowest spreadingand most isotopically heterogeneous mid-ocean ridges. Variationsin Nd–Hf isotope compositions and Lu/Hf ratios clearlydistinguish an Atlantic–Pacific-type MORB source, presentwest of 26°E, characterized by relatively low _Hf valuesfor a given _Nd relative to the regression line through all Nd–Hfisotope data for oceanic basalts (termed the ‘Nd–Hfmantle array line’; the deviation from this line is termed_Hf) and low Lu/Hf ratios, from an Indian Ocean-type MORB signature,present east of 32°E, characterized by relatively high _Hfvalues and Lu/Hf ratios. Additionally, two localized, isotopicallyanomalous areas, at 13–15°E and 39–41°E,are characterized by distinctly low negative and high positive_Hf values, respectively. The low _Hf MORB from 13 to 15°Eappear to reflect contamination by HIMU-type mantle from thenearby Bouvet mantle plume, whereas the trace element and isotopiccompositions of MORB from 39 to 41°E are most consistentwith contamination by metasomatized Archean continental lithosphericmantle. Relatively small source-melt fractionation of Lu/Hfrelative to Sm/Nd, compared with MORB from faster-spreadingridges, argues against a significant role for garnet pyroxenitein the generation of most central SWIR MORB. Correlations between_Hf and Sr and Pb isotopic and trace element ratios clearly delineatea high-_Hf ‘Indian Ocean mantle component’ that canexplain the isotope composition of most Indian Ocean MORB asmixtures between this component and a heterogeneous Atlantic–Pacific-typeMORB source. The Hf, Nd and Sr isotope compositions of IndianOcean MORB appear to be most consistent with the hypothesisthat this component represents fragments of subduction-modifiedlithospheric mantle beneath Proterozoic orogenic belts thatfoundered into the nascent Indian Ocean upper mantle duringthe Mesozoic breakup of Gondwana. KEY WORDS: mid-ocean ridge basalt; isotopes; incompatible elements; Indian Ocean     

基于表格的通用管理信息系统的设计

作者提出了一种表格式通用管理信息系统的设计方案,介绍了系统的设计思想、主要工作流程、系统各组件的功能、作用及相互关系等还详细介绍了系统主要数据库的设计。